What is innocent and non innocent ligand?

What is innocent and non innocent ligand?

In chemistry, a (redox) non-innocent ligand is a ligand in a metal complex where the oxidation state is not clear. Jørgensen first described ligands as “innocent” and “suspect”: “Ligands are innocent when they allow oxidation states of the central atoms to be defined.

What are innocent ligand?

An innocent ligand is one that binds to a transition metal in such a way that the oxidation state of the metal is able to be determined with clarity, i.e. the method of binding and the contributed charge are both unambiguous.

What is redox active ligands?

A redox-active ligand is an electron donor, acceptor, or radical molecule that can coordinate to a metal ion. As such, redox-active ligand chemistry has attracted significant attention not only within coordination chemistry research but also in materials science.

What is the opposite in meaning of innocent?

Innocent means; not guilty of a crime or offense, harmless, clear, ingenuous, not guilty, Opposites of Innocent; guilty. culpable.

What is the charge of no ligand?

NO(neutral) is nitrosyl, NO(with +1 charge) is nitrosonium and NO(with -1 charge) is nitroso, beileve me it becomes a bit confusing with this ligand when it is paired with a central metal atom of variable O.S. to guess in which state it is acting as a ligand!

What is redox active?

Protein which possesses at least one active center which mediates its participation in redox reactions, usually via reversible oxidation of a cysteine residue leading to a cysteine-sulfenic acid that can either be stabilized, or react with an unmodified cysteine residue and form a stable but reversible disulfide bond.

What does redox active mean?

Redox reactions are characterized by the actual or formal transfer of electrons between chemical species, most often with one species (the reducing agent) undergoing oxidation (losing electrons) while another species (the oxidizing agent) undergoes reduction (gains electrons).

What are redox active metals?

The most abundant redox-active metals are the transition metals iron and copper. More than 60 percent of all iron in the human body is present in the red blood cells in the protein called hemoglobin and in muscle cells in the protein called myoglobin.

What do you call an innocent person?

1 sinless, virtuous; faultless, impeccable, spotless, immaculate. 6 simple, naive, unsophisticated, artless. See synonyms for innocent on Thesaurus.com.

What is innocent and non innocent ligand? In chemistry, a (redox) non-innocent ligand is a ligand in a metal complex where the oxidation state is not clear. Jørgensen first described ligands as “innocent” and “suspect”: “Ligands are innocent when they allow oxidation states of the central atoms to be defined. What are innocent ligand? An…